complexes of Schiff's basis drivered from amino acids to acetylfuorine with their biological activity
JOURNAL OF EDUCATION AND SCIENCE,
2018, Volume 27, Issue 4, Pages 67-83
AbstractA new complexes of some transition metal ions (Co(II),Ni(II),Cu(II)) and non-transition metal ions (Zn(II),Cd(II)) with a number of Schiff bases obtained from the condensation of some amino acids isoleucine, phenylalanine and alanine with (2-acetylfuran) have been prepared. All the prepared complexes have been characterized by elemental analysis(M), molar conductance, magnetic susceptibility infrared and electronic spectral. The complexes were classified as:
1-Complexes with the formulas [ML(CH3COO) (H2O)2].
2- Complexes with the formulas [ML(CH3COO) ] H2O.
B-Homo dinuclear complexes.
Complexes with the formulas [M2(L)2(CH3COO)2] .2H2O.
L= 2-Acetyl furan isoleucine imine, 2-Acetyl furan phenylalanine imine and 2-Acetyl furan alanine imine.
The physical measurements showed that the prepared complexes have a tetra coordinated (tetrahedral) and hexa-coordinated (octahedral) structure and that all the prepared complexes were non electrolyte.
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