Physico-Chemical Studies of Reactions of Alkalytion of Schiff,s Bases
JOURNAL OF EDUCATION AND SCIENCE,
2010, Volume 23, Issue 4, Pages 1-18
The Schiff’s Bases (N-arylidene benzylamines) (1-29) have been alkylated with different alkyl halides by applying solid-liquid phase-transfer catalysis system (solid K2CO3, CH3CN, TBAB). The products were identified as the corresponding alkylated Schiff’s bases, by analyses of their spectral data (UV, IR, NMR, MS). The mechanism of the reaction was investigated on the basis of theoretical approach using semi-empirical AM1 module in the CS ChemOffice molecular modeling package.
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