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Keywords

Synthesis of Spiro Pyrrolidines
Schiff bases
Arylidene Cyclohexanones

Abstract

ABSTRACT A series of -arylidene cyclohexanones (1-4) had been prepared via Claisen-Schmidt condensation, while other series of N-arylidene benzylamines (Schiff bases 5-10) had also been synthesized by equimolar addition. The 1,3-anionic cycloaddition of Schiff bases to -arylidene cyclohexanones under basic conditions afforded the corresponding spiro pyrrolidines (11-23). The structures of the products are supported by valid spectral data and physical properties. Theoretical data had been used to support the suggested mechanism.
https://doi.org/10.33899/edusj.2008.51236
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