Print ISSN: 1812-125X

Online ISSN: 2664-2530

Volume 18, Issue 2

Volume 18, Issue 2, Winter 2006, Page 1-114


Synthesis and Characterization of Tetradentat Macrocyclic Ligands and its Complexes with Mn(II),Fe(II),Co(II),Ni(II) and Cu(II) Metal Ions

Saad K. Dawood; Israa A. Hassen; Thana Y. Yousif

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 1-10
DOI: 10.33899/edusj.2006.79265

A new complexes of Mn(II),Fe(II),Co(II),Ni(II) and Cu(II) are synthesized with a new tetradentate ligand (1,3,7,9-tetraaza-4,6,10,12-tetraoxo-2,8-dithiacyclo-dodecane) LI, (5,11-dimethyl-!,3,7,9-tetra aza-4,6,10)12-tetraoxo-2,8-dithiacyc!o-dodecane) L2,(5,6,12,13-tetra hydroxy-l, 3s 8,10-tetraaza-4?7,ll,14-tetraoxo-2,9-dithiacyclotetradecane) L3 and characterized by microanalysis (N and M),molar conductance measurments, magnatic susceptibility measurments, IR, electronic spectral studies.

Spectrophotometric Determination of Sulphadiazine in Pharmaceutical Preparations Via Arsenazo III - Cerium (III) Reaction

Nabeel S. Othman; Raeeid M Kadder

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 11-23
DOI: 10.33899/edusj.2007.163005

A simple, rapid, accurate and precise spectrophotometric method is proposed for determining sulphadiazine (SDA) in pure from and in its pharmaceutical and veterinary preparations. The method is based on oxidation-reduction reaction between SDA and cerium(IV) ion (ceric ion), then the subsequent reaction of cerium(III) with arsenazo III reagent in acidic medium to produce a green-blue complex which is stable, water soluble and has a maximum absorption at 654 nm with a molar absorptivity of 1.22*10^5 l.mol^-1. cm^-1. beer's law is obeyed in the concntration range from 1 to 10mg SDA in a final volume of 25 ml. The proposed method has been applied successfully to determine SDA in pharmaceutical and veterinary preparations.

Spectrophotometric Determination of Aniline by Azo-Dye Formation with 2, 6-Dihydroxybenzoic Acid-Application to waters

Saad EL Sultan; Inam A. Hamdon; s Nabeel S. Othman

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 24-32
DOI: 10.33899/edusj.2006.78743

A simple and sensitive Spectrophotometric method for the determination of aniline in aqueous medium is described. The method is based on the formation of a yellow coloured azo product from the diazotisation of aniline followed by a coupling reaction with 2,6-dihydroxybenzoic acid in the presence of sodium carbonate. Absorbance of the resulting yellow azo dye is measured at 432 nrn and is stable for 1 hour at least. Beer's law is obeyed in the concentration range of 5-80|ig of aniline in a final volume of 25ml, with a molar absorptivity of 4.2xl04l.morl.cm"!, a relative error of +1.13 to+ 4.40 % and a relative standard deviation of ±0.30 to ±0.76%, depending on the concentration level.
The method is successfully employed for the determination of aniline in river and waste waters.

Spectrophotometric Determination of Promethazine in Pharmaceutical Preparations

Sh.H. Mohamad; Sh.L Al-Najafi; AM. Al-Abachi

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 33-41
DOI: 10.33899/edusj.2006.78831

A batch and flow injection (FIA) spectrophotometric methods have been developed for the determination of promethazine in aqueous solution and in pharmaceutical preparations. The methods are based on the reaction of promethazine with sulphanilic acid in the presence of N-bromosuccinimide as oxidizing agent. The water soluble bluish- green dye produced is measured at Xmax 600 nm, linearity is observed from 2-30 and from 2-100 p-gml"1 promethazine with detection limits of 0.20 and 0.43 ^ig ml"1 promethazine by batch and FIA procedures, respectively. The effect of chemical and physical parameters has been carefully considered and the proposed procedures have successfully been applied to the determination of promethazine in pharmaceutical formulations.

Synthesis of Some New Pyrazolines

A.J. AL-Hamdany; A.M. Hamdy

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 42-50
DOI: 10.33899/edusj.2006.79263

The present work includes the preparation of a series of substituted chalcones ( NO2 , Me , OMe , Cl ) and condensation of these chalcone with a series of prepared aromatic and aliphatic acid hydrazides in a basic medium to afford the new pyrazolines . Physical and spectral methods were used to confirm the structures .

Synthesis and Characterization of Multinuclear Complexes with Pyridylthiolato Selenium (IV) and their Adducts with Neutral Ligands

Wajida L Alhamadani; Nabeel H. Buttrus

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 51-58
DOI: 10.33899/edusj.2006.78741

Selenium metal react with di-pyridyl disulfide (Py2S2) in refluxing toluene to give the compound [Se(Spy)4] through oxidative addition reaction. Multinuclear complexes of the general formula [Se(Spy)4(MCl2)2] and [Se(Spy)4(MCl2)4J were prepared by a direct reaction of CoCl2.6H2O, NiCl2,6H2O or CuCl2-4H2O with the selenium compounds. Adducts of trinuclear complexes with 1,10-phenanthroline were also prepared and having the general formula [Se(Spy)4(MCl2)2(Phen)2]. The prepared complexes and their adducts were characterized by their metal analysis, IR and UV/Vis spectroscopy, conductivity and magnetic measurements.

Evaluation of the Antibacterial Activity of Cyperus rotundus Extract (An in vitro study)

Ghada Younis Abdul-Rahman; Aveen Hawal Rasoul

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 59-63
DOI: 10.33899/edusj.2006.79264

The Cyperus rotundus tubers are commonly used in folk medicine in many countries as antiparasitic antidepressive and etc ...... The antibacterial effect of the
aqueous extracts of this plant was evaluated using selected Gram positive and Gram negative bacteria and microdilution technique.
The results showed a significant inhibitory effect of 10-2 and 10-3 dilutions of the aqueous extract on all the tested Gram negative but not the Staphylococcus aureus.
Key Words: Cyperus rotundus, antimicrobial activity.

Measurements of Some Plasma Parameters of Hybrid Discharge in Air at Moderate Pressure

S.K. AL-Hakary

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 64-77
DOI: 10.33899/edusj.2007.78830

In abnormal glow discharge in air under (D.C) excitation at different pressures in varying both frequency and amplitude of radio frequency field. Measurements of some plasma parameters such as (axial and radial electric field, electrical conductivity of positive column and electrical conductivity of glow discharge between the electrodes) have been reported for various currents discharge by using double probe method. The results show that the radial distribution of both axial and radial electric field measured between probes is nearly exponential and increases with the increasing A.C amplitude. This will in turn the conductivity of the positive column decreasing, furthermore to that he variation of axial electric field between electrodes with both frequency
and A.C amplitude is nearly inversible leading to increasing electrical conductivity between electrodes according to that. The electrical conductivity between electrodes proportional linearly with the gas pressure, while the electrical conductivity of the positive column proportional inversely with gas pressure.

Semi-Standard Tableaux of Young Between Algebra and Computer Programming

Ammar S. Mahmood; Ayad H. Abdul Qader; Yahya K. Ibrahim

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 78-93
DOI: 10.33899/edusj.2006.78740

Since the representation theory start, the mathematics science especially in algebra began to open many new researches such our this one, we start from Schur algebra in his new representation described by Green [6], passing through his relation with semi-standard tableaux according to Green.
The number of these tableaux still unknown, so we tried hardly to find the mathematical rule for this problem, but as these tableaux become great, the counting of them become difficult. Therefore, we tried to write an algorithm and a program to do so. As a result, we find the appropriate mathematical rule.

Wavelet Methods Used to Solve a System of Linear Equations

Riyad Mubarak Abdullah; Kais Ismail Ibraheem

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 94-103
DOI: 10.33899/edusj.2006.78829

In this paper, we study the comparison among many methods to solve a system of linear equations based on the principle of wavelet methods as a Daubechies wavelet, Haar wavelet, Meyer wavelet, Symlet wavelet, Mexican Hat wavelet, Morlet wavelet.
As a result, the Haar wavelet method can be considered the best method to solve the linear equations compared with the other methods especially for the dense and sparse matrix. For the three diagonal matrices the Meyer wavelet gave a good results. Other conclusion was found that the Symlet wavelet needs a long time to solve this system of equations and for all types of the matrix.

Determination of ionization constants for some aromatic Schiff base acids derived from a benzyl compound with aromatic amines

Adel S. Azzoz; Mahmoud S. Saeed; Khalil I. Al-Nuaimi

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 1-10
DOI: 10.33899/edusj.2006.79299

ABSTRACT
The paper is concerned with the preparation and determination o'f pKa for four acidic Schiff bases from the reaction of benzil with other appropriate aromatic primary amines as o,m,p-aminophenols and 4-amino-2-hydroxybenzoic acid. This produces two categories of acidic Schiff bases having a mono phenolic groups in o.m and p-positions and diacidic Schiff base containing a nieta phenolic and para carboxyl group with respect to amine group respectively.
The structures of imines under study are confirmed by using some physical methods as melting points, UV, IR and NMR spectra.
The potentiomeric method is applied for the determination of pka values of these acidic compounds. This is founded to be fast, simple and precise with an accuracy in the range of ± 0.001 pka unit.
The pka values of mono phenolic Schiff bases are found to depend on the positions of phenolic groups on aromatic ring and in the order of increasing para > ortho > rneta. Moreover, the pka of diacidic Schiff base resulted to the evaluation of pka of phenolic group only, with a failer determination of pka value of the carboxyl group. A fixed 25% ethanol -water mixture is used through pKa determination Finally, a suitable interpretation for the last is given and discussed.

Effect of Eugenia caryophyllus clove essential oil and its active ingredients on the growth of a number of Cram-positive and negative bacteria

Muthana J. Mohammed; Omer M. Ramadan; Ragheed Y. Ghazal

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 11-19
DOI: 10.33899/edusj.2006.79280

In this study, the essential oil was isolated from dried flower buds of Eugenia caiyophyllus (clove), then the eugenol and the acidic compounds were isolated from the essential oil. The inhibiting effect of these compounds were investigated on growth of some bacteria which are: Bacillus subtilis, Staphyhcoccus aureus, Pseudomonas aenighiosa> Escherichla coli Proteus mirabilis and Salmonella typhi. The steam distillation was used to isolate the essential oil while the chemically active extraction was used to isolate eugenol and neutral compounds. The eugenol was identificated by Thin layer chromatography (TLC) plate and determination the Rate of flow (Rf) of it.
The essential oil showed better inhibiting effect on the all bacteria which was used in this study compared to commercial antibiotics as a control. Also, eugenol was showed an inhibiting effect on the all bacteria which was compared to commercial antibiotics but it's effect was stronger than the effect of essential oil. The neutral compounds have no effect on Ps. aeruginosa and Prof, mirabilis., but have an inhibiting effect which are less than that indicated for essential oil and eugenol compound compared to a control (Augmentin and Ciprofloxacin).

Effect of hydrogen peroxide and saturated animal fats on blood lipids level of adult male rats

Khalid H. Shareef; Maan S. Kallo

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 20-41
DOI: 10.33899/edusj.2006.79295

Thirty two albino male adult healthy rats were used as a biological and experimental model for this study, their body weight ranged between 250-275g and aged 3-4 months. They were divided according to the body weight into four groups. The first group considered to be control group, feed ordinary diet and normal drinking water, the second group feed ordinary diet and giving 0.5% H2O2 in freshly prepared drinking water, which contains oxygen and hydroxyl free radicals. The third group feed atherogenic diet (normal diet containing 4.69% saturated animal fats and 0.26% cholesterol) and normal drinking water, and the fourth group feed atherogenic diet and 0.5% HjC^ in drinking water for 30days experimental period. Nutritional status (body mass, afford diet, eliminated feces, liver, heart, kidney weights and diet lipid absorption) were estimated. Serum total lipid, cholesterol, triglycerides, phospholipids and various lipoproteins were determined, atherogenic indices were calculated and the malondialdehyde levels of liver, heart, kidney tissues were estimated. Analysis of variance and Duncan multiple tests showed the highly effect of 0.5% HsOz with/without saturated animal fats and cholesterol, was caused a decrease in body mass, ingesting diet weights and body absorbable lipid and increase values of serum total lipids, cholesterol, triglyceride, very low density and low density lipoproteins, In addition, it caused an increase values of atherogenic indices and a decrease in high density lipoprotein. Also the atherogenic diet alone was caused a similar affect of hydrogen peroxide on rat's nutritional status and serum lipid profile, therefore, the interaction affect of those two agents together was caused increase values of rat serum lipids, lipoproteins, malondialdehyde and a decrease in high density lipoprotein value.

Effect of different temperatures on the amount of itaconic acid produced from molasses of reed by local strain of Aspergillus terreus

Esmaeel T. Almetewte

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 42-51
DOI: 10.33899/edusj.2006.79296

This research covered a determination of itaconic acid produced from cane molasses by a local strain of Aspergttlus terreus by the influence of different degrees of temperature depending on the optimum conditions of growth & productivity of the microorganism including the 5th day of incubation , 12.5% sugar concentration in the production medium , 0.35% of urea as nitrogen source, 0.20% of potassium dihydrogen phosphate, 0.15% of both of magnesium sulphate and calcium chloride , 100 RPM of rotating shaker, these values which refer to the optimum conditions of growth & productivity of itaconic acid gave an optimum amount of acid produced equal to (812 ) mg100ml of the medium.
The acid produced was determined according to Friedken method & separated by using thin layer chromatography technique (TLC) , finally the acid produced was identified by using the Nuclear Magnetic Resonance Spectrometer (NMR).

A study on calcareous particles in hepatic worm Fasciola gigantica (Platyhelminthes: Trematoda) in Ninawa Governorate, northern Iraq

Sundes N. Alkallak; Bothena H. Alsabaawi; Sahera E. Hameed

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 52-64
DOI: 10.33899/edusj.2006.78832

Trematoda, which belong to platyhelminthes resemble many living organisms which have the ability to produce mineral concentrations and constitute as so called calcareous corpuscles, which were investigated in the present study in F, Gigantica, using Von Kossa technique.
Results revealed the existence of calcareous corpuscles which were abundantly distributed in the potential organs with high metabolic functions like excretory, digestive and reproductive system, as well as the parenchyma. Whereas, they appear less abundante in the ventral sucker. On the ather hand the skin lacks the corpuscles, as the results of the present study, clear the aim of its performance to explain the centralize location, biological importance and the functional role of these corpuscles, leading to an increase in the limited available informational background for investigation on separation and distribution of the calcareous corpuscles and their roles which interact with its variable metabolic activities adult worm F.gigantica. The present work may be considered first in Ninevah province north of Iraq.

Causes of urinary tract infections in people with diabetes compared to those without diabetes

Zeyad T. Alrassam; Adeeba Y. Shareef

JOURNAL OF EDUCATION AND SCIENCE, Volume 18, Issue 2, Pages 65-75
DOI: 10.33899/edusj.2006.79300

The study includes the isolation and identification of bacteria causing urinary tract infection (UTI) for 372 diabetic patients , 125 of them were males , 247 females and 95 healthy controls , their ages ranged between 11-71 years. The study showed that UTI caused by different micro organisms at a rate of 66.13% of the diabetic patients , 69.9 % of them were females , while 30.1 % were males , UTI increased significantly with age in both sexes especially after the age of 40 years for diabetic non-insulin dependent patients . UTI in diabetic patients was caused by different genera of bacteria compared with those in non-diabetic as the bacteria isolated was CUrobacler ,Serratia , Morganella , Salmonella , Staph. Epidermidis and Alcaligens in diabetic patients only , in spite of the different types of bacteria isolated E.coli , Klebsiella and Staph. aurleus showed a prevalence among the other causes in spite of the different isolation rates of both groups.